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[Prospects of Nuclear Energy in India 
Sankar Hajra
Substance of the paper: In this article, in a  context of  nuclear energy generated by France in 2004  we present evidence showing that (A) burn-up energy  per gram of  Uranium is within 75, 154 KcalsH and  83,722  KcalsH , (B)  analyses of energy expenditure show that   commissioning  & decommissioning of reactors,  waste disposal and after-Fukushima-surveillance work  require 38,223 Kcals per gram of Uranium burn-up, (C)  fuel viability of Uranium prepared from ores containing 0.067% or more Uranium  may be  positive,  but  that  prepared from   0.01% Uranium Ore is   negative,  (D) foreign  carbon-dioxide emissions to produce  10,500  tonnes  of   Uranium that France imports from foreign countries, each year,  total about 62.7  million tonnes for 0.067%  ores  and 420.2  million tonnes for 0.01% ores per year, (E) hidden  Carbon-di-oxide emission   relating to yearly  burn �up of  10, 500 tons of  Uranium is 183 million tonnes   distributed over half a century in aggregate  before and after the  reactor-life-time, and finally (F) France�s  nuclear power is in no way more competitive or lower cost than many of other options for supplying electric power.  
Energy expenditure for preparing  Uranium  from  various grades of ores  have been determined  (on the basis of the analyses of the Olympic Dam data of  Australia as given by IAA) in columns (1) and (2)  and surplus energy for each grade are given in column (3).
(Burn �up energy per gram of Uranium 80,000 Kcals; Energy Expenditure for reactor commissioning &decommissioning etc.  per gram of Uranium burn up  38,223 Kcals).


Percentage of Uranium per gram in  the ore

(1)Energy expenditure for preparation of Uranium Kilocalorie per gram
(2)Surplus Energy  Kilocalorie per gram of Uranium
(3)
= 80,000"[38,223+(2)](i)  0.0676,764+35,013(ii) 0.059,064+32,713(iii) 0.0145,319"3542(iv) 0.14,532+37,245(v) 0.22,266+39,511(vi) 0.41,133+40,644
The  study in the main  paper  present evidence for  the propositions  (A) & (B);  and (B) implies(E).  Figures given in column (3)  of (i) and (iii)  suggest (C). Figures in column (2)  of  (i) and (iii)   in terms of fossil fuel expenditure suggest (D).We have reviewed too France�s Nuclear Energy Economy that suggests the proposition as given in (F). Therefore, we may naturally ask the  nuclear technologists of India:  if France has no better or  little better  utility of Uranium fuel processed from 0.3 % ores than coal ,  how India will get benefit using her  0.01 %  domestic grades of Uranium ores  or  0.1% grades of Uranium ores  imported from Niger? ]
Kindly note that the substance of the paper given above is not for publication. 

Prospects of Nuclear Energy in India 
Sankar Hajra*
Indian Physical Society, Kolkata
Email :  HYPERLINK "mailto:sankarhajra@yahoo.com" sankarhajra@yahoo.com
Abstract: In this article, in a  context of  nuclear energy generated by France in 2004  we present evidence showing  that  fuel viability of Uranium prepared from ores containing 0.067% or more Uranium  may be  positive,  but  that  prepared from   0.01% Uranium Ore is   negative.  Therefore, we may naturally ask the  nuclear technologists of India:  if France has no better or  little better  utility of Uranium fuel processed from 0.3 % ores than coal ,  how India will get benefit using her  0.01 %  domestic grades of Uranium ores  or  0.1% grades of Uranium ores  imported from Niger? 
Key Words:  Real fuel , Nuclear Electricity, Energy-investment, Energy-return, intrinsic cost advantage, carbon-di-oxide emission, 
 Introduction: 
France declares that about 78 % of electricity produced by the country is 'nuclear origin'. France also claims this is 'low CO2'. Another common claim by French governmental sources is that French nuclear electricity is abundant and cheap. We argue in this article that this is not the case.
*Corresponding author, Sankar Hajra, Indian Physical Society,  2A & 2B Raja S.C.Mullick Road, Kolkata-700032, Mobile  Phone: 8820063766, Email : sankarhajra@yahoo.com

Real fuel and 'false fuel' 
To know whether a fuel is real fuel or not is to determine whether the fuel has a positive net energy-yield (energy-return) i.e., the fuel produces greater amounts of energy when it is used than the energy investment  in extracting the fuel from basic raw materials  and making, processing, transporting  as well as disposing of residues of the fuel. A huge amount of energy is obtained when Hydrogen, Aluminium or thermite (a mixture of powdered aluminium and oxides of iron) are burned. But energy obtained from combustion of those fuels is not greater than the energy spent to make them from natural resources. Therefore, hydrogen and thermite cannot be treated as real fuels. Electricity could be readily generated from combustion of those fuels but electricity made from those fuels will be more energy-expensive than electricity made from coal or petroleum. Hydrogen and Aluminium, although seemingly prospective as fuels, are actually false or energy-negative fuels. Similarly, it is said by nuclear technologists that one thermal MW day energy is required to produce 0.9 gram of Plutonium.
 (Calculation 1:
 0.9 gram of  Plutonium is made by using 1000�1000� 60�60�24/4.2 Cals [Feiveson 2004].
1 gram of Plutonium is made by using 1000�1000� 60�60�24/(4.2�0.9) Cals =23�106 Kcals.
Caculation 2:
Fission of a kilogram of plutonium-239 can produce an explosion equivalent to 21,000 HYPERLINK "http://en.wikipedia.org/wiki/TNT_equivalent" \o "TNT equivalent"tons of TNT (Wiki 2013a),	
1 gram of Plutonium  239=21 ton TNT=21000,000,000 Cals=21�106 Kcals.)
Therefore, 23�106 Kcals  of heat energy are required to make one gram of plutonium but, that amount of plutonium yields  EMBED Equation.DSMT4  Kcals  of heat by way of fission  as per  [Wiki 2013a] and   EMBED Equation.DSMT4 Kcals  of heat by way of fission as per Encyclopedia Britannica [Sg. 1959] . 
 Hence, plutonium just like hydrogen and Aluminium is a false fuel. False fuels may serve as real fuel only when they are available as formerly useless by-products and benefit from 'upstream energy subsidies'.
Primary Energy Supply in France
 Now, to analyze the claims of France, we need to know (a) how much fossil fuel and renewable fuel (hydroelectricity, geothermal energy, waste-to-energy, wind turbines, solar photovoltaic and CSP), as well as gas by-products of industry such as blast furnace gases used in France as primary fuel supply, (b) Electricity generated and  (c) French final consumption for the end uses of energy.
We give below France�s primary energy supply and final consumption of energy in 2004 as per France �Energy Mix Fact Sheet [ EC  2011 France].












Table 1. Energy mix fact sheet-France-2004

MtoePrimary
supplyDomestic ProductionNet importsFinal
ConsumptionElectricity Generation
(TWh)Solid fuels14.10.513.34.825.8Oil92.81.794.174.05.9Gas39.21.737.833.421.2Nuclear115.6115.6448.2Electricity-5.335.8Renewables17.317.4-0.19.966.0Other-5.35.2Total273.7136.4139.8157.9572
 (Mtoe = Million ton oil equivalent, TWh = Trillion Watthours)
 Fuel viability of Uranium Fuel used by France
  World Nuclear Association mentions that 20 % of France�s nuclear electricity generated (448.2 TWh)  comes from  recycled materials [WNA 2013].  16.7 TWh electricity went only to Tricastin Uranium Enrichment Plant to enrich Natural Uranium [Wiki 2013b]. France�s   nuclear reactors consumed 10,500 tonnes of Uranium [WNA 2010; Wiki 2011].  Therefore from 10,500 tonnes of Uranium, France got  (448.2"89.6"16.7) TWh= 255 TWh electricity in 2004.
(Calculation 3:

341.9 TWhE  EMBED Equation.DSMT4   Cals E  EMBED Equation.DSMT4 CalsH
(Ratio of heat to electricity is considered here 3: 1)

Quantity of Natural Uranium Fuel Used  10,500 tonnes     

Heat energy released  per 1 gram of Uranium EMBED Equation.DSMT4 CalsH=  83,722 KcalsH)

This amount of heat is 49%  of the  burn up energy  per gram of Uranium as given by the official  claim: 171, 420 Kcals per gram of Natural Uranium [ Ramanna 1975] .
In Table 1 (Energy Mix fact sheet), we see that France in 2004 used 92.8 Mtoe  of petroleum as primary energy supply. But Index mundi [IM 2011] mentions the figure as 100.3 Mtoe (732 million barrels = 100 Mtoe).
 In the same table  we see that in 2004  France used 14.1 Mtoe of coal as primary energy supply, but other data sources such as CMM Global Overview [CMMGO 2010 ] and Source Watch [SW 2011]  provides figures as  14.8 Mtoe . Therefore, we may conclude that France might have used 154.3 Mtoe of fossil fuels in 2004 and not 146.10 Mtoe. 
In case France used 154.3 Mtoe of Fossil fuel  as per Index Mundi, CMM Global Overview and Source Watch instead of 146.1 Mtoe of Fossil fuel as per European Commission,  
heat energy released per gram of Uranium  will be 75, 154 KcalsH instead of 83,722  KcalsH. 
This study upholds our proposition (A): burn-up energy  per gram of  Uranium is within 75, 154 KcalsH and  83,722  KcalsH.
Energy Expenditure for  Plant Operation, Plant Building & Decommissioning ,  Waste Disposal  and after Fukushima Surveillance
Nowadays (2010), reactor installment cost is 9 b$ per  reactor  and  decommissioning , waste disposal and after Fukushima surveillance  cost 9 b$ per  reactor .  
Energy expenditure  for these  two performances=  1/6th of the total cost (say)= 3 b$ per  reactor . This suggests that energy expenditure  for plant building,  decommissioning,  waste disposal  &  after-Fukushima-surveillance  is 38, 223 Kcals per gram of Uranium .

(Calculation 4:
$71.25 were   the price of 907.2 kg of coal as on 2010.
We could get 9,072 00/71.2 grams =12,741 grams of coal per dollar. 
Nuclear Reactor life time  is 30 years (say), Total reactors in France  are 60 (say), Uranium consumed by France each year 10500 tons (say).
Every reactor in its life time has burnt-up 10,500�30/60 tons of Uranium=5250 tonnes of Uranium (equivalent enriched Uranium).
=5250�1000�1000 grams  of  Uranium .
Reactor installment cost is 9 b$ per  reactor  + decommissioning , waste disposal and after Fukushima surveillance  cost is  9 b$ per  reactor  =18 b$ per  reactor . 
As per World Steel Association  [WSA 2014] , energy constitutes a significant portion of the cost of steel production from 20%-40% in some countries.  To commission and to decommission a  nuclear reactor, similar proportion of energy cost  is plausible.  Therefore,  we may consider that  energy expenditure  for these two performances = 1/6th of  18 b$  =  3 b$ per  reactor  
For burn up of 1 gram of Uranium (or equivalent  enriched Uranium),  energy expenditure ( for reactor installment & decommissioning  (along with waste disposal and after-Fukushima-surveillance  )  cost  = 3,000,000,000 / (5250�1000�1000) dollars=0.6 dollar
Coal used =12,741�0.6 grams  a"12,741�0.6� 5  Kcals=38, 223 Kcals.
Proportionate Energy expenditure for reactor installment & decommissioning (along with waste disposal  and after-Fukushima-surveillance) to burn  up 1 gram of Uranium ( or equivalent  enriched Uranium) =38, 223 Kcals).
This upholds our proposition (B):  analyses of energy expenditure show that   commissioning  & decommissioning of reactors,  waste disposal and after-Fukushima-surveillance work  require 38,223 Kcals per gram of Uranium burn-up
Now let us find what amount of energy was spent to prepare that amount of Uranium from its available ores?
Status of Uranium as fuel, real or false?
Uranium is not available in nature in a free state.  It is available in ores. Recent Uranium mining activities are constrained to use ores that contain only 0.01-0.05 % of Uranium [Herring 2004, Diehl 2011]. In actual practice, taking account of mining and operation losses, many Uranium mines process approximately 2000 grams of their ores to yield  1 gram  of natural Uranium. The ore is treated with various chemicals to separate Uranium from other ingredients [Hyett 1984]. To produce those chemicals, heat energy is abundantly required. Now,  heat required for chemical processes comes generally from the combustion of fossil fuels. Therefore, to prepare  Uranium fuel,   fossil fuels are required in the long run.  But the essential question is: how much fossil fuel is required to get 1gram of Uranium from its now available ores? We give a simple study to elucidate  this problem below.
After preliminary concentration to remove sand and clay, the ore is leached with sulphuric acid and treated with an excess of the acid and then with hydrogen sulphide to precipitate all metallic radicals other than Uranium. The filtrate is then treated with an excess of ammonium hydroxide to precipitate Uranium as ammonium diurate which is ignited to prepare U3O8. This U3O8 is reduced to UO2 by hydrogen. The di-oxide is converted into Uranium fluoride by heating it strongly in gaseous hydrogen fluoride. The fluoride is then reduced to the metal by means of pure metallic calcium. However, now a-days selective tertiary amines are used to separate Uranium from the leached solution of the ore. 
Sulphuric Acid, Hydrochloric Acid, Hydrogen Sulphide, Sodium Carbonate, Ammonium Hydroxide, Hydrogen and Calcium are not available in nature. In the ultimate analysis, fossil fuels and other chemicals are required   to prepare those elements and compounds. We may now tabulate the energy interplayed/ involved/ used or required in making those basic chemicals needed to extract natural Uranium from its ores.
Generally, the volumes of chemicals needed in any manufacturing process will be twice the theoretically calculated minimal volumes. This is partly due to processing energy required for the upkeep or maintenance of the production system and other technical formalities to be maintained for the operation.
We may study the situation from well known verifiable data. To produce highly pure Uranium from an ore with 0.05% Uranium, chemical energy expended is given below:
 Energy interplayed / involved to manufacture basic chemicals used to extract Uranium from its ore. 
In the Uranium extraction process basic chemicals are sulphuric acid, hydrochloric acid, hydrogen sulphide, ammonia and sodium carbonate and now a day tertiary amines. We are first tabulating energy interplayed/ involved to manufacture sulphuric acid which takes the key role to extract Uranium from its ores.

i) Manufacture of Sulphuric acid:	

 EMBED Equation.3 	 EMBED Equation.3 				(1)

 EMBED Equation.3    EMBED Equation.3 	 EMBED Equation.DSMT4 			(2)

 EMBED Equation.3 	 EMBED Equation.DSMT4 				(3)

 EMBED Equation.3 		�H = " 312Kcals / mol			(4)	

Theoretically calculated minimum interplaying energy		 EMBED Equation.3  

Actual interplaying energy						 EMBED Equation.3 

ii) Synthesis of tertiary amines like Alamine 336:
Energy involved to synthesize Alamine 336 is not known.

 Energy Cost of Uranium Fuel: Energy interplayed to separate metallic radicals other than Uranium from   ores with little Uranium content  
Laboratory preparation of Uranium from an ore with 0.05% Uranium content.

Let us extract 1 gram of Uranium from an ore of Uranium with quartz- pebble conglomerates .   And let the Uranium content of the ore mixture be 0.05 percent.  Besides U3O8  this ore contains the oxides of  Silicon, Iron, Molybdenum , Nickel, Aluminium, Calcium, Magnesium, Copper, Cobalt, Manganese, Sodium , Potassium, Fluorine,  Vanadium, Titanium, Carbon,  Sulphur,   Phosphorus and rare earths and gangues. Let us assume for simplicity that this ore contains no gangues. 
Now    2000 gms of the ore  will contain  1998.8 gms  oxides and other salts of the elements other than  1.2 gm of   U3O8 ,  which through proper chemical separation should give 1 gm of  natural Uranium at the final stage. In this analysis we shall calculate approximately the total amount of energy consumed in the separation process not so far tabulated and even considered by the nuclear energy experts. 
Let us assume for simplicity that impurities present are only Aluminium oxide weighing 1998.8 gms.  
In that case leaching with excess Sulphuric Acid will make Aluminium Oxide to Aluminium Sulphate and a very small quantity of the acid will be consumed by U3O8   so that Uranyl Sulphate could be formed as per the following reactions:
 102	+ 294 =		342+ 54
 EMBED Equation.3 						(5)
(Calculation 5:
102 gms of Aluminium oxide require 294 gms of Sulphuric Acid
1998.8 gms of  Aluminium Oxide require  EMBED Equation.DSMT4  of Sulphuric Acid 
Therefore energy expenditure  is 624�5760/98 Kcals= 36,676 Kcals.)
Another 50% of energy should be required for the process of  pre-concentration, tertiary amine manufacturing, liquid -liquid separation, drying, calcining,  reduction and giving shape to the yellow cakes.  Therefore to get 1 gram of natural Uranium from 0.05%  Aluminium Oxide ore,  a maximum  73,352  Kcals  of heat  energy should be  used theoretically.

The ores with Lithium ( AW-7), Sodium (AW-23), Potassium (AW-39)  Beryllium (AW-9), Magnesium(AW-24) Aluminium (AW-27), Silicon (AW-28), Phosphorus (AW-31) and Sulphur(AW- 32)    will require approximately the same amount of Sulphuric acid   to leach  2000 gms of the mixed ores. 
But the ores with Calcium (AW-40), Titanium (AW-48), Vanadium (AW-51), Chromium (AW-52), Manganese (AW-55), Iron (AW-56), Cobalt (AW-59), Nickel (AW-29), Copper (AW- 64) and Zinc (AW- 65) will require 2418  gms of  Sulphuric acid for  acid leaching of  that  ore  to the minimum. . 
Therefore, to leach 2000 gms of any arbitrary  ores of the above composition, minimum 2418 gms of Sulphuric acid are required. Energy expenditure to make 2418  gms of Sulphuric acid   is   EMBED Equation.DSMT4 15,396  Kcals.  
( Calculation 6:
81   + 98    =	161+ 18		
 EMBED Equation.DSMT4 				(6)
81  gms of Zinc oxide require 98  gms of Sulphuric Acid for leaching
1998.8 gms of Zinc Oxide require  EMBED Equation.DSMT4  of Sulphuric Acid for leaching.  Energy expenditure 2418�624/98 Kcals=15,396 Kcals. )  
Another 50% of energy should be required for the process of  pre-concentration, tertiary amine manufacturing, liquid -liquid separation, drying, calcining,  reduction and giving shape to the yellow cakes.  
Therefore to get 1 gram Uranium from 0.05% Zinc Oxide ore,  an approximate   30,792  Kcals  of heat  energy should be  used theoretically. [High atomic weight dominant ores should require much less Sulphuric acid for leaching].  
Uranium Exporter countries have expended the above amount of theoretical energy to extract Uranium from national mining reserves in order to supply that Uranium  to France. 
Most of the Uranium ores contain heavy metals. In those cases, Sulphuric acid required for leaching will be much less. In the case where most of the Uranium retain in gangues, sulphuric acid requirement for leaching will be further diminished.
 As said before, French nuclear reactors in 2004 produced only 342 TWh of electricity from 10,500 tons of Uranium, but the energy required to produce that  Uranium fuel  from available Uranium ore (0.05% Uranium content) should be assessed independently. 
Therefore, we like to demonstrate below the energy expenditure of a real famous Uranium manufacturing unit, Olympic Dam (having ores with  0.067 % Uranium content)  operating during the last decade of previous century.

 Illustrative Example: Olympic Dam 
 
The process of Uranium separation from the low Uranium content ore is tedious, troublesome and  energy consuming. It starts from mining. Uranium is highly toxic and it attacks kidney. It is claimed that it causes birth defects and increases the risk of leukemia. People working in the Uranium mines are exposed to the direct radiation of Uranium. Miners are to inhale Uranium ore dust which accumulates in the lungs and causes lung cancer. Moreover, Uranium emanates Radon. Miners are to breath in air contaminated with Radon which causes lung cancer. 
Olympic Dam of South Australia produces one seventeenth of the total Uranium production of the world.  (Total Uranium production in 2011 all over the world was 54, 610 tonnes, Uranium production of Olympic Dam of South Australia was 3, 258 tonnes in that year). Average Uranium content of the ores of this site is 0.067%.  

 We are tabulating below the energy required to separate 1 gram of Uranium from its now available ores. 
Uranium extraction from low Uranium containing ores is done through the following processes now a day [IAA1993, 19-24].
Mining:  Mining first starts with Open Pit mining and  as the  ore depth increases , 
Underground mining become advantageous. Rock fragmentation is generally done through the use of explosives. For loading hydraulic or electrical shovels are used. Then Ores are classified and sorted as per radiometric gradation and transferred for milling. Mining waste are treated and disposed. Dosimetric survey of the mining workers is conducted. Total energy expenditure to operate machineries and to prepare the explosives is not known.
  Crushing, Grinding and Roasting:  Sorted ores are crushed and ground for leaching either with acids or alkalis. Total energy expenditure to operate the machineries is not known. A secondary ball mill works here with a work index of 16KWh/ton.
Leaching: Crushed and ground ore are treated with acids in five mechanically agitated tanks maintained  with 550-600 centigrade by injection of steam.
Solid Liquid Separation. Energy required is not known
Solvent Extraction Process: Different chemicals are used in this process to separate Uranium. Energy expenditure to prepare those chemicals are not known.
Precipitation with Magnesium Oxide, Ammonia and Hydrogen Peroxide. Energy expenditure to prepare those chemicals are not known.
Drying/ Calcining.
Product Recovery.
Waste Management. Energy expended for waste management is high. But any reliable data is not available.
Water required   in Olympic Dam
In the Olympic Dam after leaching and solid �liquid separation, . Uranium is extracted in three stages using an amine-kerosene solvent in Krebs mixer settlers. The solvent system is   3 % Alamine 336 in Shellsol 2046 diluted with 2% idodecanol as a modifier. The extraction circuit is operated in the organic continuous mode, with solvent recycling to give an O/ A ratio of 1.5-1.7:1 in mixer. In solvent extraction, alamine 336 is used in a kerosene diluents, and the phases move counter currently.�The loaded solvents may then be treated to remove impurities. First, cations are removed at pH 1.5 using sulfuric acid and then anions are dealt with using gaseous ammonia. The solvents are then stripped in a countercurrent process using ammonium sulfate solution. Precipitation of (NH4)2U2O7 (ammonium diuranate) is achieved by adding gaseous ammonia to neutralize the solution .The diuranate is then dewatered and roasted to yield U3O8 product, which is the form in which uranium is marketed and exported. 

We shall analyze here energy expenditure per gram of Uranium produced in the Olympic Dam Uranium mine which may provide us with some realistic picture.  Energy expenditure in most of the operations excepting the following four is unknown. Energy expenditure of the three known processes is  given below.
 A secondary mill with work index of 16 KWh /ton is used for crushing.  Equivalent heat energy 41, 143 Kcals / per ton of  the ore that contains 670 grams natural Uranium.
(Calculation 7: 
Energy expenditure  to crush 1 ton of the ore =16�103�3600�3/4.2 Cals =41,143 Kcals 
Energy expenditure per gram 41, 143/670Kcals=			61.4 Kcals)

Chemicals used to extract Uranium of this site are as follows [IAA 1993, 289-297]:
Sulphuric Acid  330 Kgs per ton ; Sodium Chlorate 2kgs per ton; Sodium Xanthate (amount unknown); Methyl Isobutyl carbynol(amount unknown); Caustic Soda (amount unknown); Coagulants (amount unknown); Oxime Kerosene Solvent (amount unknown);  3% Alamine (amount unknown);  2% Isodecanol (amount unknown);  Ammonium Sulphate (amount unknown);  Sodium Carbonate (amount unknown);  Ammonia (amount unknown);   Oxygen  (amount unknown);  Lime Slurry (amount unknown);   Shellsol 2046 diluent (amount unknown). 
Diesel/ Electricity Operated Machineries are as follows:
Sizing grizzly; jaw-crusher;  vibrating feeder; conveyer belt; automatic bathing system;  primary autogeneous  mill;  pump, secondary ball mill; Dorr Oliver two cell assemblies; thickener; automatic Lasta pressure filter; CCD circuit;  Larox high rate filter;  coagulator; sedimentary clarifier; multimedia AbTech sand filter; CCD thickener; washing cyclone; centrifuge; screw conveyor; high energy Venturi type scrubber; multiple hearth Skinner furnace; smelter; Ahlstrom waste heat boiler; Flakt electrostatic precipitator etc.
1ton  of Olympic Dam Ore requires 330 Kgs of Sulphuric acid for only leaching and the solution eventually produces 670 gms  of Natural Uranium.  Heat energy expenditure =330�103�624/98  Kcals = 2,101,224 Kcals / ton  of the ore  that contains 670 grams Natural Uranium.
[We have consulted natural Uranium preparation in the Olympic Dam mine  of Australia during 1993. This mine processes ore with 0.067 % Uranium content by weight.  IAEA 1993 writes that this mine uses 330 Kgs of Sulphuric acid per tonne to leach the ore contrary to Siedel�s statement (1979) that a maximum 100 Kgs of Sulphuric acid  per tonne are required for leaching  (which is however meant  for ores with varied  Uranium content starting  from about 0.02% to 0.2% .) 
In  the  Kazakhstan mines   as per   �in-situ leach  of uranium�  40kgs to 80 kgs of  Sulphuric  Acid are required  per kg  of  Uranium produced . But  the  uranium content of  the ores are  not stated.  Beverly Uranium mine  of  Australia  contains uranium oxide at  0.18 grade Uranium  as per   �in-situ leach  of uranium�  and required  7.7  Kg of Sulphuric Acid per Kg Uranium produced.  For 0.05 or far lower grade Uranium ores, Sulphuric Acid consumption will be much higher even  more than ten times of the given measures. 
It is well known that in many parts of Europe and the Commonwealth of independent states embraced in situ technology for the mining and extraction of  Uranium. Many of these sites are left now as catastrophic legacies of radioactively contaminated sites facing significant environmental clean-up costs, radiological hazards and underground water contamination with radioactivity and metal poisoning. Therefore, in situ leaching is not likely to be continued in near future.]

(Calculation 8: 
Energy expenditure per gm of Uranium for leaching: 2101224/670 Kcals=	3136 Kcals)		
During leaching of 1 ton of the ore,  leaching tanks should be maintained at 600 C .  
Energy expended for this process 40,000 Kcals per ton of the ore.

(Calculation 9: 
Minimum energy required to maintain this temperature= 1�106�40 calories = 40,000  Kcals / ton ore  are required considering no radiation loss.
	Energy expenditure per gram =						60 Kcals).
The Olympic Dam uses 35  million liters   Great Artesian Basin water each day making it the largest industrial user of underground water in the southern hemisphere.  This water is pumped along the underground pipe line  from two bore fields  which are located 110 Kms and 200 Kms north of the mine . The salty water is desalinated  before  it is  used.  Contaminated water from the mine is passed through a series of sealed ponds where it evaporates.   Pumping  out of this huge amount of  water  from the Great Artesan Basin is drying the nearby mound springs  for which the aridity of the region is increasing and  in consequence many rare and endemic species in the region are in danger. The mine produces 3965 tons of Uranium per year [Wiki 2013c] 
( Calculation 10: 
0.003965 Million tons  of Natural  Uranium require 12775 Million liters of water. 
1 ton of Natural Uranium requires 12775/ 0.003965 = 3221942   liters of water 
1gm of Natural Uranium requires 3221942/ 106 =3 liters of water.	

Energy requirement to desalinate 1000 liters of saline water   is  approximately 15 KWH [ Wiki 2013d].
Energy requirement to desalinate 3 liters of water  
= 15�3�1000�60�60�3/(4.2�1000) calories= 				116 Kcals.

According to California State Water Project [Wiki 2013e] average distance travelled by water is 240 KM whereas   that distance travelled by water current to reach Olympic Dam is 115 Km [Wiki 2013c]

Energy expended to bring 1 acre feet (1�233�482 litres) from an average  distance  of 240 Km,  3000 KWh electricity is required (Wilkinson 2013).
Energy expended to bring 3 litres of water from a distance of 115 Km =3000�1000�60�60�3�3�115/ (4.2�1233482�240�1000) Kcals=		9 Kcals)
Total energy expenditure to continue only those four   operations  (ore crushing, leaching, temperature maintenance, desalinization of water required, and water transport)   is  61+3136+ 60+(116+ 9) Kcals=  3382  Kcals  per gram of Uranium produced.  Therefore if we consider all the chemical and physical processes  undertaken for Uranium preparation in Olympic Dam, (3,382 Kcals�2)  =6764  Kcals /gram Uranium produced  must have been required for an ore with 0.067% Uranium content.  

=6764 Kcals

[Frank Von Hippel et al  state that  with current  (1975) technology, the electrical power energy investment in the fuel averages  is  approximately   five percent of the electrical energy output of the plant. 
According to the official nuclear technologists of modern times,  it is said that energy requirement from mining to conversion is 0.3% of the burn up energy generated. We have shown in our paper that the energy requirement for 0.067% ores  from mining to  Natural Uranium preparation  is about 8% of the burn �up energy of that Uranium. This figure may turn to be 57% for  0.01% ores. ]
We may prepare a chart of energy investment  for  preparation of 1 gram of natural Uranium from  Uranium ores with varied Uranium content  and surplus energy available from I gram of  Uranium burn-up depending on the grade of ores.

Table II. Surplus Energy per gram of Uranium Burn-Up
[Burn �up energy per gram of Uranium 80,000 Kcals; Energy Expenditure for reactor commissioning &decommissioning etc.  per gram of Uranium 38,223 Kcals].
Percentage of Uranium per gram in  the ore

(1)Energy expenditure for preparation of Uranium Kilocalorie per gram
(2)Surplus Energy  Kilocalorie per gram of Uranium
(3)
= 80,000"[38,223+(2)](i)  0.0676,764+35,013(ii) 0.059,064+32,713(iii) 0.0145,319"3542(iv) 0.14,532+37,245(v) 0.22,266+39,511(vi) 0.41,133+40,644

Figures given in column (3)  of (i) and (iii)  suggest the proposition  (C) :   fuel viability of Uranium prepared from ores containing 0.067% or more Uranium  may be  positive,  but  that  prepared from   0.01% Uranium Ore is   negative. 	 

Therefore, we may conclude that as per French data Uranium obtained from ores with 0.067%  Uranium  may be  a real fuel. But Uranium produced from  ores with 0.01% Uranium could hardly be considered as a real fuel. Rather that Uranium is false fuel.

Is nuclear power really low-carbon? 
There was a time when promoters and defenders of atomic energy would utilize slogans such as, � Let us go play in the nuclear power park�  [Gofman & Tampler 1973]. But nowadays it is well known that from mining to nuclear waste management, Uranium and other nuclear materials have always caused radiation hazards. Similarly, the modern or most recent slogan utilized by atomic people is that nuclear electricity is "clean", but this has declining credibility. A British based research group writes [Burke  et al. 2011]:
Credible academic analysis of the full Life Cycle shows that nuclear power emits many more times the amount of greenhouse gases (GHG) than renewable (for the same amount of electricity). Some analysts argue that within the lifespan of the proposed UK program, Uranium will be so rare that mining it will release as much GHGs as efficient gas-burning. There are huge uncertainties in calculating nuclear power�s GHG emissions. Any claims that nuclear is �very low carbon� should be treated with skepticism � let alone the PR hype that nuclear is a �zero-carbon� source of electricity. Analysis of the GHG impacts of nuclear disasters (particularly regarding Fukushima) has not yet been done. 
In our study we have shown that to extract 10,500 tonnes of Uranium   from   now-available ores, energy  required in ultimate analysis  is equal to  EMBED Equation.DSMT4 Kcals . 
 The exporter countries have used fossil fuels equivalent to the combustion of  8.9 million tonnes of carbon  that have emitted 32.6 million tonnes of Carbon-di-Oxide in their own countries to produce that Uranium and this saved France from further Carbon-di-Oxide pollution.
 
(Calculation 11:

To produce 1 gram of Natural Uranium extracted from 0.067 %  ores  6764  Kcals of heat energy are  required.. Therefore, if 0.067 % ores are used, to produce  10500 tonnes  of Natural Uranium  
 6764 �10500�106   EMBED Equation.DSMT4 Kcals  of heat energy is required.
Now, 1 gram of  Carbon burns with oxygen to give 8 Kcalories of heat energy and 11/3 grams of Carbon dioxide.
Therefore, Exporter countries have burnt  EMBED Equation.DSMT4   tonnes of carbon =8.9  million tonnes of carbon (or equivalent petroleum) to that Uranium.)

 	Therefore, Exporter Countries have produced   8.9�11/3 =32.6  million tonnes of Carbon dioxides and polluted their own countries with that carbon dioxide which has saved France from further pollution. 
Therefore, in terms of fossil fuel expenditure the data analysis suggests the proposition (D): Exporter Countries (if uses 0.067% Uranium ores) have produced   32.6 million tonnes of Carbon dioxides and polluted their own countries with that carbon dioxide which has saved France from further pollution. If 0.01% ores are used, 218.4 million tonnes of carbon-di-oxide would be emitted.
 Now  France  has already expended ( many years before the operating  of the reactor)  and yet to be expended ( for a period of many  years  after shutting down of the reactor) 38, 223 Kcals of energy per gram of Uranium. In that case a further  183 millions tons of Carbon-di-oxide   has been emitted and yet to be emitted  covering a long period   to burn �up yearly 10500 tonnes of Uranium by France   which has not contributed to the present yearly carbon-di-oxide emission scenario  from nuclear energy heading and therefore  has remained hidden.
(Calculation 12:  
Hidden Carbon di oxide emission for burn-up of 10500 tons of Uranium yearly by France:

38, 223�1000�1000�10,500 / (8�1000�1000) tonne carbona"(38223�10500/8 ) tonnes of Carbon=50 million tonnes of Carbon a"183 million tonnes of Carbon-di-oxide).
 
This analysis suggests  our proposition  (E) :  proportionate  hidden  Carbon-di-oxide emission  for commissioning  of the reactor to  burn  up  that Uranium and the reactor�s  subsequent decommissioning   is 183 million tonnes   distributed over half a century in aggregate  before and after the  reactor-life-time

 French nuclear power--not cheap
D. B. Lilienthal, the first Chairman of the Atomic Energy Commission of USA, commented in 1961 that the tapping of energy from nuclear source seems to be a mirage. He wrote: �The new world of atomic plenty does not exist.�  He openly criticized the USA Government for the huge expenditure of public funds on nuclear electricity, which was more costly than electricity obtained from coal [Lilienthal 1963].
In 1976 Miller mentioned that nuclear taxes have been levied indirectly in USA but do not show up on electric bills, and commented that from an economic standpoint alone, relying on nuclear fuel  as the primary source of national stationary (electric) energy would be economic lunacy on a scale unparallel in economic history and could lead to an economic Waterloo for the United States [Miller 1976]. 
Starting from the last part of the 1970s , many critics of US nuclear policy vehemently argued against the claims by US officials that nuclear electricity was cheap. They notably accused nuclear energy and power accounting of being misleading.  They argued that nuclear electricity is supplied at low cost because of large federal grants and subsidies, and most economic estimates of the cost of nuclear power were biased because they do not include the cost of subsidies and other aid programs [Desaix 1977].
From the 1990s to the present, Indian studies corroborate the views  of the western critics. S. Bhattacharya & S. Mukherji  in 1993  were moved to declare that nuclear power is actually a bluff [Bhattacharya & Mukherji 1993]  whereas Ramana et al. in 2005 were confident enough to say that  �This contradicts numerous claims by the DAE (Indian atomic energy agency) that nuclear power is cheaper than coal-fired thermal power at sites which are 800-1,000 km away from coal mines. Nuclear power plants, therefore, have been and remain a costlier way of trying to address India�s electricity needs, than coal based thermal plants�[ Ramana et al. 2005].
In a  MIT study  of 2003 the participants  confess that  in deregulated markets, nuclear power is not now cost competitive with coal and natural gas. However, plausible reductions by industry in capital cost, operation and maintenance costs, and construction time could reduce the gap. Carbon emission credits, if enacted by government, can give nuclear power a cost advantage [MIT 2003]. 
Andrew MacKillop  [McKillop 2011; McKillop 2012a-e] in a series of articles  has commented that nuclear power is not cheap. 
In a letter dated 17 May 2011, the French Prime Minister asked the Cour des Comptes to prepare, as part of its national accounting mission to assist the French Government with a report on �the costs of the nuclear power sector� to be submitted before 31 January 2012. The Cour des Comptes  has published the summary  report on 31 January, 2012  and the actual report on June 21, 2012 (CCSR 2012, CCMR 2012). 
 The Cour des Comptes report shows that end of life and dismantling costs are, not surprisingly the most challenging factor, and its report takes many precautions in its calculating methods and bases. Its data tables suggest that an average likely cost in euros of 2010 value, of 3.8 billion euros 2010 for each  of the 63 main civil reactors of France, will probably be the spending provisions required, starting in the immediate and up to 2025[CCMR 2012, 269]. 
Through 2012-2025, if not provided 10-year operating life extensions, at least 11 French reactors will need decommissioning, for a total cost through a time period of up to, or more than 30 years ahead, of around 32 billion euro in euro 2010  [CCMR 2012,  86].  Other data in the report suggests that prolonging the operating lifetime of these reactors, and other reactors in the French 'fleet' will require the spending of 55 billion euros2010 in the period 2012-2025, for additional safety and maintenance provisions[CCSR 2012, 17].
The Cour des Comptes provided details on as many previous and historical known costs of French nuclear power that it was able to identify. It estimated that French nuclear power, through 1957-2011 received a total of around 228 billion euros2010 from the Public sector and the operators [CCMR 2012, 270 ) . It received 38 billion euro2010 in the form of government-funded nuclear R & D [CCMR 2012, 285] and an initial investment of 96 billion euro2010 (CCMR 2012, 266) in the 58 current reactors that presumably has come from the State.

 The Real Economic Costs of Nuclear Electricity
The report estimated that the  Current Economic Cost  ( with extension of life expectancy investment (Generation 2, PWR) is  54 Euro2010/MWh  [Percebois  2012] and  Current Economic Cost  ( without  extension of life expectancy investment (Generation 2, PWR) is 49.5 euro2010/ MWh [Percebois 2012]; but this was billed by EDF the former state monopoly electricity provider, and present owner of all French nuclear plants at 33.4 euro2010 per MWh [CCSR 2012, 14]. It went on to state the obvious: power prices must rise soon, and by 15% to start with, in the absence of government subsidy decisions. Several scenarios are shown in the report, mostly in the range of a 33%-50% rise in French bulk electricity prices by as soon as 2017. The Cour des Comptes notes that future nuclear power was unlikely to be cheaper than 80 euro2010 /MWh (Paris 2012)
 Maintenance costs for the French nuclear plants are estimated by the Cour des Comptes as more than doubling, from 1.5 billion euro2010-per-year, to 3.7 billion 2010 in the next decade, to 2022 [CCMR 2012, 269] with much of the rise "front loaded" to the period 2012-2017. This alone will push power prices up another 10%-15% from current prices, the report estimated [CCSR 2012, 11]. 
Fuel reprocessing and waste disposal costs, the Cour des Comptes estimates will grow at about 6% per year, at least doubling in the next 12 years. Overall, long term waste stockpiling and safekeeping through the next 10-15 years was estimated as likely to cost 22 billion euros2010 [CCMR 2012, 226], not far behind the early and initial costs of reactor dismantling and Safestor. 
 Alternatives to nuclear power - for France

Since the first wave of nuclear reactors in 1970 to the on-going construction of Generation III+ reactors in Finland and France, nuclear power seems to be doomed to a cost escalation curse. If the curse is not stopped, according to L�v�que nuclear power competitiveness will be compromised [L�v�que 2013].

This Cour des Comptes report, given some attention in mainstream media but often treated as reassuring - it made no calls for immediate retirement of France's oldest reactors, like Fessenheim - clearly underlines that nuclear power was not, and cannot ever have been chosen merely on cost grounds. It was expensive in real terms in the past and will be even more expensive, and dangerous in the future.
For many reasons but especially the intimidating future cost curve or reactor building and waste handling, and its massive debt load mainly due to nuclear power, EDF has delayed on ordering new reactors and has sought "new nuclear" sales opportunities outside France, as in Finland and the UK. One result the Cour des Comptes indicates is now certain: unless given operating life extensions and due to reactor retirement and dismantling, France would need to build at least 22 new EPR in less than 12 years, to maintain nuclear supplies at about 75% of all French electricity supply, and keep pace with forecast demand growth. 
The Cour des Comptes  has avoided  to suggest  on alternative and available non-nuclear generating options ranging from wind power and solar PV, to gas, coal, hydropower, wave power, geothermal and biomass energy [CCMR 2012g]. In the UK scenario, it seems that electricity generated from off shore wind is cheaper than nuclear electricity (Paris, 2012). In India electricity produced from coal must be much cheaper than electricity produced from metallic Uranium.
This analysis suggests the proposition  (F):  France�s nuclear power is in no way more competitive or lower cost than many of other options for supplying electric power.

  France and her export of nuclear reactors / nuclear fuel 

The Cour des Comptes study shows that France has not much benefited herself in energy sector from her nuclear fuel/ nuclear electricity as she professes. This fourth biggest weapons trader in the globe has benefited herself in this sector through trade with other countries. At the expenditure of foreign energy, she gets her nuclear fuel. At the cost of foreign pollution, she has been able to make her own country clean. If France could get the market of other countries (generally of very poor third world countries like India) to sell her nuclear fuel / nuclear reactor  abundantly, she will supply nuclear electricity to her own people at no cost at  the cost of the people of the countries that will buy nuclear commodities from her. However, exporter countries have not always used 0.067%  ores  (which we have studied in this article) to produce natural Uranium. They in many cases have used rich ores to produce that Uranium. But that activity is transient and countries like India will not get that advantage if they buy Uranium mines in Africa.

 Therefore, France�s claim is no more than the reflection of her business motivation. However, some countries rich in various types of energy resources produce much less nuclear electricity (approximately 20%) such that their energy mix data mask the energy expenditure to manufacture nuclear electricity. 
If they produce much more nuclear electricity, their energy mix data will prove the same thing as in the case of France. The pressure and publicity of those countries, too, for nuclear electricity reflect the same motivation as that of France.
Prospects of Nuclear Energy  in India
 France generally  uses Uranium ores with 0.3% Uranium content and  according to the official nuclear specialists one gram of Natural Uranium possesses a burn-up energy of 1,74, 000 Kilocalories. Still France�s real cost of 1 unit of electricity is little less than the real cost of 1 unit of energy generated from coal which gives only 8 kilocalories of heat per gram. Therefore,   from reactor building  to disposal, a huge amount of energy and special materials that consumes energy too have been used for these operations  and this  has made the metal fuel practically of no better utility than coal .

In the present decade available Uranium ores for India will not contain Uranium more than 0.01% .   Energy expenditure per gram of Uranium produced from this ore should be  87, 235   Kcals /per gram.   Taking into account  reactor installation,  reactor management,  decommissioning of the reactors  ,  radioactive disposal and after- Fukushima-Surveillance work,   energy expenditure for preparation of  1 gram of Uranium and its utilization will be much higher than above value.  It may be 2 or 3  times  of energy per gram of Uranium produced whereas the maximum  burn-up energy  of 1gram of Uranium is 87, 725 Kcals.

Most of the ore available in India, Pakistan and Korea rarely contains more than 0.01 % Uranium. Therefore, in any case, these countries in the prevailing scenario should never expect   to gain energy-profit from using Uranium fuel for their energy needs if they use their own Uranium ores or they buy ores of the same grade from Africa.
However, India has taken some initiative to collect Uranium from Niger. Most of the ores from Niger contain 0.047%-0.11% Uranium as given below and India will hardly be able to snatch Niger mines with high grade Uranium   from the tight fists of France and China. 

Table III. Niger Uranium Reserves and Resources in 2009 ( from World Nuclear Association updated 2013)

End 2009ReservesResources��proven�probable�measured�indicatedinferredSOMAIR15,200 tU @ 0.22%7971 tU @ 0.29%10,712 tU @ 0.086%�4453 tU @ 0.11% 11,367 tU @ 0.21% COMINAK8460 tU @ 0.338%16,210 tU @ 0.337%- 639 tU @ 0.39% 25,223 tU @ 0.27% Imouraren - TD42,583 tU@ 0.11%�94,386 tU @ 0.1%--6798 tU @ 0.098%�Imouraren - TS11,936 tU @ 0.047%34,615 tU @ 0.046%�-8612 tU @ 0.078%�3329 tU @ 0.046%��Azelik--13,000 tU @ 0.2%--�Madaouela���20,000 tU19,600 tU
In the meantime,  sporadic suicidal  bomb attacks in the Uranium  mines  have started in Niger and  after the bomb attacks on May 23, 2013, Areva  has suspended its works in the Uranium mines in the Agadez and Arlit region. 
 Our Question
  Therefore, we may naturally ask the  nuclear technologists of India:  if France has no better or  little better  utility of Uranium fuel processed from 0.3 % ores than coal ,  how India will get benefit using her  0.01 %  domestic grades of Uranium ores  or  0.1% grades of Uranium ores  imported from Niger? 

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�"�2d�^�2a$gdvT�$�2d��^�2a$gdvT�$�2d��*$^�2a$gdvT�����#�����������������������G�R�g�h�s���î�����r�]H]H]H3)h��h3F�B*CJOJQJ^JaJph)h��h�V�B*CJOJQJ^JaJph)h��hvJ2B*CJOJQJ^JaJph)h��h&LB*CJOJQJ^JaJph#h�M�B*CJOJQJ^JaJph)h��hf�B*CJOJQJ^JaJph)h��hl(B*CJOJQJ^JaJph)h��h^/�B*CJOJQJ^JaJph)h��hD<�B*CJOJQJ^JaJph#hC�B*CJOJQJ^JaJphs�u�v�w���������Q�j�m�������������D����걜�eeHH3)h��hZ<QB*CJOJQJ^JaJph9h��hyLB*CJOJQJ^JaJmH	@nH	phsH	@tH	3h�czB*CJOJQJ^JaJmH	@nH	phsH	@tH	9h��h�b�B*CJOJQJ^JaJmH	@nH	phsH	@tH	)h��hX�B*CJOJQJ^JaJph)h��hfsnB*CJOJQJ^JaJph#h�czB*CJOJQJ^JaJph#h�M�B*CJOJQJ^JaJph)h��h�y�B*CJOJQJ^JaJphD�E�I�O�R�i�k����������3�`��������igLiL14h&H�h�EB*CJOJQJ]�^JaJnH	phtH	5h��h�EB*CJKH$OJQJ^JaJnH	phtH	U/h&H�B*CJKH$OJQJ^JaJnH	phtH	5h��hD"�B*CJKH$OJQJ^JaJnH	phtH	#h&H�B*CJOJQJ^JaJph#h�czB*CJOJQJ^JaJph)h��haB*CJOJQJ^JaJph)h��h$UB*CJOJQJ^JaJph)h��h�b�B*CJOJQJ^JaJphNuclear Power in France, World Nuclear Association
(Updated September 2013) viewed on 02-10-2013
HYPERLINK "http://www.world-nuclear.org/info/Country-Profiles/Countries-A-F/France/"http://www.world-nuclear.org/info/Country-Profiles/Countries-A-F/France/
WSA (2014), Fact Sheet Energy, World Steel Association  viewed on 23-02-2014
HYPERLINK "http://www.worldsteel.org/dms/internetDocumentList/fact-sheets/Fact-sheet_Energy/document/Fact%20sheet_Energy.pdf"http://www.worldsteel.org/dms/internetDocumentList/fact-sheets/Fact-sheet_Energy/document/Fact%20sheet_Energy.pdf
Table 1. Energy mix fact sheet-France-2004

MtoePrimary
supplyDomestic ProductionNet importsFinal
ConsumptionElectricity Generation
(TWh)Solid fuels14.10.513.34.825.8Oil92.81.794.174.05.9Gas39.21.737.833.421.2Nuclear115.6115.6448.2Electricity-5.335.8Renewables17.317.4-0.19.966.0Other-5.35.2Total273.7136.4139.8157.9572
 (Mtoe = Million ton oil equivalent, TWh = Trillion Watthours)



Table II. Surplus Energy per gram of Uranium Burn-Up

[Burn �up energy per gram of Uranium 80,000 Kcals; Energy Expenditure for reactor commissioning &decommissioning etc.  per gram of Uranium 38,223 Kcals].
Percentage of Uranium per gram in  the ore

(1)Energy expenditure for preparation of Uranium Kilocalorie per gram
(2)Surplus Energy  Kilocalorie per gram of Uranium
(3)
= 80,000"[38,223+(2)](i)  0.0676,764+35,013(ii) 0.059,064+32,713(iii) 0.0145,319"3542(iv) 0.14,532+37,245(v) 0.22,266+39,511(vi) 0.41,133+40,644

. 






Table III. Niger Uranium Reserves and Resources in 2009 ( from World Nuclear Association updated 2013)

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Youez - 2016 - github.com/yon3zu
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