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Hindi Journal of Chemistry and Applied Chemical EngineeringISSN : 2576-3954
Linert W Author
Subjects of specialization
Affiliation
Chemistry, Thermo Dynamics, Thermal decomposition, Mechanistic aspects, Combustion
Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-AC, A-1060 Vienna, Austria
Biography
Linert W; Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-AC, A-1060 Vienna, Austria. One of his references is, "Vinodkumar CR, Nair MKM, Radhakrishnan PK (2000) Thermal studies on lanthanide nitrate complexes of 4-n-(2′-furfurylidene) aminoantipyrine. J Therm Anal Calorim 61: 143-149."
Publications
Research Article Open Access
Ligand Field and Counter Anion Effects on the Thermal Stability of Copper(II) Complexes of 1,2-Di(imino-4’-antipyrinyl)ethane and 4-N-(4’-antipyrylmethylidene) aminoantipyrine
Author(s): Madhu NT, Knittl EK, Tesfay GA, Bekele GM, Sirak TB and Linert W
A comparative thermolytic investigation on copper(II) complexes with two antipyrine Schiff base derivatives, namely 1,2-Di(imino-4’-antipyrinyl)ethane (GA) and 4-N-(4’-antipyrylmethylidene) aminoantipyrine (AA), with different counter anions like perchlorate,nitrate, chloride, and bromide has been done by thermogravimetric and derivative thermogravimetric analysis. The present investigation reveals that the counter anions and the ligand field play a big role on the thermal stability of the copper (II) complexes of both Schiff base derivatives. For the present complexes, the thermal decomposition mechanism has been investigated according to Šatava, which follows a ‘random nucleation with one nucleus on each particle, i.e. the Mampel model’.
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