Journal of Nanomaterials & Molecular NanotechnologyISSN: 2324-8777

All submissions of the EM system will be redirected to Online Manuscript Submission System. Authors are requested to submit articles directly to Online Manuscript Submission System of respective journal.

Bundlet Model of Single- Wall Carbon, BC2N and BN Nanotubes, Cones and Horns in Organic Solvents

Bundlet Model of Single- Wall Carbon, BC2N and BN Nanotubes, Cones and Horns in Organic Solvents

The existence of Single-wall C-nanocones (SWNCs), especially nanohorns (SWNHs) and BC2N/Boron Nitride (BN) analogues is discussed in organic solvents in cluster form. A theory is developed based on the bundlet model, describing distribution function by size. The phenomena present unified explanation in the model, in which free energy of (BC2N/BN )SWNCs involved in cluster, is combined from two components: volume one proportional to the number of molecules n in cluster and surface one, to n1/2. The model enables describing distribution function of (BC2N/BN )SWNC clusters by size. From geometrical differences, bundlet [(BC2N/BN )SWNCs]/ droplet (C60/B15C30N15/B30N30) models predict dissimilar behaviours. Various disclination (BC2N/BN )SWNCs are studied via energetic/ structural analyses. Several (BC2N/BN )SWNC’s ends are studied, which are different because of closing structure and arrangement type. Packing efficiencies and interaction-energy parameters of (BC2N/BN )SWNCs/SWNHs are intermediate between C60/ B15C30N15/B30N30 and (BC2N/BN )Single-wall C-nanotube (SWNT) clusters: in between behaviour is expected; however, properties of (BC2N/BN )SWNCs, especially (BC2N/BN )SWNHs, are calculated closer to (BC2N/BN )SWNTs. Structural asymmetry in different (BC2N/BN )SWNCs, characterized by cone angle, distinguishes properties of types: P2. BC2N/BN, especially species isoelectronic with C-analogues, may be stable.
 

Special Features

Full Text

View

Track Your Manuscript

Media Partners

GET THE APP